Preparation of hydrocarbons from synthesis gas

Details Preparation of hydrocarbons from synthesis gas Preparation of hydrocarbons from synthesis gas

1984-06-29

1986-06-17

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Group viii metal containing catalyst utilized for the...

518709, 385638, 385733, C07C 104

Patent

active

045957037

ABSTRACT:
A process wherein an admixture of carbon monoxide and hydrogen is contacted over a cobalt catalyst, especially a thoria promoted cobalt catalyst, formed by dispersing the cobalt, or cobalt and thoria, upon a titania or titania-containing support wherein the titania support is one having a rutile:anatase ratio of at least about 2:3, and preferably at least about 3:2 to produce, at reaction conditions, a distillate fuel constituted principally of an admixture of linear paraffin and olefins, particularly a C.sub.10 + distillate which can be further refined and upgraded to high quality fuels, and other products such as mogas, diesel fuel, jet fuel, lubes and specialty solvents, particularly premium middle distillate fuels of carbon numbers ranging from about C.sub.10 to about C.sub.20.

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Lisitsyn et al., Institute of Catalysis, Siberian Branch of the Academy of Sciences of the USSR, Novosibirisk Translated from Kinetkai Kataliz, vol. 23, No. 4, pp. 919-931, Jul.-Aug. 1982.
92:129385h; The Synthesis of Solid Hydrocarbons from Methanol; Shima, Kensuke, Morita, Tauyoshi (Miyazaki Univ., Miyazaki, Japan); Nouveau Journal DeChime, vol. 6, No. 10-1982, p. 459.
Fischer-Tropsch Synthesis of Hydrocarbons Over Ruthenium Supported on Transition Metal Oxides; Kikuchi, Nomura, Matsumoto and Morita (Waseda University, Tokyo 160); Pan-Pacific Synfuels Conference, vol. I, Nov. 17-19, 1982 Tokyo, pp. 1-10.
Fischer-Tropsch Synthesis Over Titania-Supported Ruthenium Catalysts; Kikuchi, Matsumoto, Takahashi, Machino and Morita (Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, Japan); Printed in the Netherlands; Applied Catalysis, 10 (1984), pp. 251-260.

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