Preparation of hydrocarbon mixtures from syngas

Chemistry: fischer-tropsch processes; or purification or recover – Group vib metal containing catalyst utilized for the...

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518713, 518728, 502 61, 502 63, 502243, 502250, C07C 104

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active

045074046

ABSTRACT:
A process is described for preparing gasoline boiling range hydrocarbons with a high iso-paraffins content from syngas having a H.sub.2 /CO mol. ratio between 1.0 and 5.0 over a catalyst mixture comprising a methanol synthesis component which contains zinc and one or more metals selected from the group consisting of chromium, copper and aluminum and a crystalline metal silicate with ZSM-5 structure which contains SiO.sub.2 and one or more oxides of a trivalent metal A selected from the group consisting of aluminum, iron, gallium, rhodium, chromium and scandium, and wherein the SiO.sub.2 /A.sub.2 O.sub.3 molar ratio is higher than 10; and which catalyst mixture has been prepared by spray-drying followed by calcining at a temperature between 425.degree. and 525.degree. C.

REFERENCES:
patent: 4086262 (1978-04-01), Chang et al.
patent: 4338089 (1982-07-01), Schaper et al.
patent: 4385193 (1983-05-01), Bijwaard et al.

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