Preparation of highly branched chain oligomers

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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C07C 224

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044763425

ABSTRACT:
Oligomers of olefins containing from 3 to about 6 carbon atoms such as dimers may be obtained in a more highly branched chain compound by effecting the oligomerization at temperatures in the range of from about 50.degree. to about 350.degree. C. and a pressure in the range of from about 100 to about 2500 psig in the presence of a catalyst comprising a fluorided aluminum phosphate. The catalyst may be prepared by impregnating an aluminum phosphate with a fluorine-containing compound in an aqeous or nonaqueous medium, drying, calcining and recovering the desired catalyst.

REFERENCES:
patent: 2060871 (1936-11-01), Ipatieff

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