Preparation of high molecular polytetramethylene adipamide

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528336, C08G 6928

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active

044607628

ABSTRACT:
A process is described for the preparation of high-molecular weight white polyamides, substantially consisting of units of --NH--(CH.sub.2).sub.4 --NH--CO(CH.sub.2).sub.4 --CO--, by the after-condensation of a corresponding low-molecular prepolymer, consisting substantially of a molecular chain of units of --NH--(CH.sub.2).sub.4 --NH--CO(CH.sub.2).sub.4 --CO--, in which process the prepolymer which is employed has been prepared in the presence of an excess of 0.5 to 15 moles-% of 1,4-diaminobutane with respect to the quantity stoichiometrically equivalent to the adipic acid applied. This prepolymer is thereafter subjected to the after-condensation reaction in the solid phase in an atmosphere containing water vapor.

REFERENCES:
patent: 2130948 (1938-09-01), Carothers
patent: 3676400 (1972-07-01), Kohan et al.
patent: 3840500 (1974-10-01), Ryffel et al.
Ogato, "Polycondensation", Article, Published 6/10/74, w/translation.
Journal of Polymer Science, Polymer Chemistry Edition, vol. 15, (1977), pp. 537-545, Gaymans et al.
Polymer Molecular Weights, Part I, Slade, 1975, pp. 1-4.

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