Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1978-04-05
1979-09-18
Levin, Stanford M.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
260 336A, 260 5, 5263402, C08F 450, C08F 452
Patent
active
041683579
ABSTRACT:
There is disclosed a method for the preparation of very high cis-1,4-polypentadiene which comprises polymerizing cis-1,3-pentadiene, also known as cis-piperylene, with a ternary catalyst system comprising (A) a soluble chromium compound such as chromium salts of organic acids, organic complex compounds of chromium containing tridentate organic ligands, and .pi.-bonded organochromium compounds, (B) an organometallic, such as trialkylaluminums, dialkylmagnesiums or dialkylzincs, and (C) dialkyl hydrogen phosphites.
REFERENCES:
patent: 3300467 (1967-01-01), Natta et al.
patent: 3429940 (1969-02-01), Wadsworth
patent: 3754048 (1973-08-01), Wu et al.
patent: 3804913 (1974-04-01), Goodwin
patent: 4048418 (1977-09-01), Throckmorton
Journ. Polym. Sci. 51, 463 (1961).
CA 80, 4644m (1974).
CA 80, 109590v (1974).
Suchma Charles J.
Throckmorton Morford C.
Clowney J. Y.
Levin Stanford M.
The Goodyear Tire & Rubber Company
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