Preparation of high cis-1,4-polypentadiene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 336A, 260 5, 5263402, C08F 450, C08F 452

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041683579

ABSTRACT:
There is disclosed a method for the preparation of very high cis-1,4-polypentadiene which comprises polymerizing cis-1,3-pentadiene, also known as cis-piperylene, with a ternary catalyst system comprising (A) a soluble chromium compound such as chromium salts of organic acids, organic complex compounds of chromium containing tridentate organic ligands, and .pi.-bonded organochromium compounds, (B) an organometallic, such as trialkylaluminums, dialkylmagnesiums or dialkylzincs, and (C) dialkyl hydrogen phosphites.

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patent: 3754048 (1973-08-01), Wu et al.
patent: 3804913 (1974-04-01), Goodwin
patent: 4048418 (1977-09-01), Throckmorton
Journ. Polym. Sci. 51, 463 (1961).
CA 80, 4644m (1974).
CA 80, 109590v (1974).

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