Preparation of hexene-1,6-dioic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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567595, 567522, C07C 5700, C07C 5100

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active

053548876

ABSTRACT:
Hexene-1,6-dioic acids, e.g., hex-3-ene-l,6-dioic acid, are prepared by reacting carbon monoxide and water with at least one diacyloxylated butene in a polar, aprotic and basic solvent, in the presence of a catalytically effective amount of palladium values, optionally a halide, and at least one inorganic halide, the cation of which being an alkali or alkaline earth metal and the anion of which being a chloride or bromide.

REFERENCES:
patent: 3686299 (1972-08-01), Carraro et al.
patent: 4611082 (1986-09-01), Chan et al.
patent: 4925973 (1990-05-01), Deweerd et al.
patent: 5179231 (1993-01-01), Denis

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