Preparation of guanidinium 5'5-azotetrazolate

Organic compounds -- part of the class 532-570 series – Organic compounds – Azo

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C07D25706, C07C27902

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058773002

ABSTRACT:
A process for the preparation of a guanidinium 5,5'-azotetrazolate by reacting 5-aminotetrazolate monohydrate with potassium permanganate in an aqueous hydroxide solution to form sodium 5,5'-azotetrazolate dihydrate as an intermediate, then reacting 5,5'-azotetrazolate dihydrate with guanidine nitrate or guanidine chloride to obtain guanidinium 5,5'-azotetrazolate.

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