Preparation of gossyplure

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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560236, 560247, 260665R, 260665G, 556 52, 556187, 568 1, 568 7, C11C 302

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046094989

ABSTRACT:
Process for the production of the insect sex attractant, gossyplure, is provided. The process comprises first disproportionating 1,5-cyclooctadiene and 1-hexene to give 1,5,9-tetradecatriene, then metallating the triene to form a 1-metallo-5,9-tetradecadiene, and finally treating the organometal compound with a C.sub.2 -synthon to give directly 7,11-hexadecadienyl acetate or a substituted 7,11-hexadecadienyl moiety which can readily be converted to the desired acetate.

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