Preparation of .epsilon.-caprolactone

Details Preparation of .epsilon.-caprolactone Preparation of .epsilon.-caprolactone

1984-06-18

1986-07-22

Fan, Jane T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D31304

Patent

active

046021140

ABSTRACT:
A process for the production of .epsilon.-caprolactone wherein 4-penten-1-ol is reacted carbon monoxide in the presence of a ligand-stabilized Pd(II) catalyst complexed with a Group IVB metal halide.

REFERENCES:
patent: 3061614 (1962-10-01), Sweeney et al.
patent: 3700706 (1972-10-01), Butter
patent: 3859319 (1975-01-01), Mrowca
patent: 3919272 (1975-11-01), Knifton
patent: 3952020 (1976-04-01), Stapp
J. Org. Chem., vol. 41, No. 17, pp. 2885-2990 (1976) Knifton.
Preprints, Div. of Petroleum Chemistry, Inc., Symposium on Homogenous Catalysis, American Chemical Society, Houston, Tex., Mar. 23-28, 1980, pp. 368-371.
Carbon Monoxide in Organic Synthesis by Jurgen Falbe, Translated by C. R. Adams (1970), pp. 157-159.

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