Preparation of epoxysilicon compounds using rhodium catalysts

Details Preparation of epoxysilicon compounds using rhodium catalysts Preparation of epoxysilicon compounds using rhodium catalysts

1990-09-17

1992-12-08

Marquis, Melvyn I.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07F 702

Patent

active

051699621

ABSTRACT:
A method for making an epoxyfunctional organosilicon compound is provided, comprising the step of reacting at a temperature of from about 25.degree. to about 100.degree. C. a mixture comprising (A) an ethylenically unsaturated epoxide; (B) an organohydrogenpolysiloxane or organohydrogensilane; and (C) a rhodium complex catalyst selected from the group consisting of:

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J. F. Harrod and A. J. Chalk, "Organic Syntheses via Metal Carbonyls", vol. 2, I. Wender and P. Pino, editors, John Wiley, N.Y. 1977.
J. L. Speier, Adv. in Organomet. Chem., vol. 17, pp. 432-434.

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