Preparation of electrically conductive polyarylene compounds hav

Details Preparation of electrically conductive polyarylene compounds hav Preparation of electrically conductive polyarylene compounds hav

1983-08-02

1984-12-18

Barr, Josephine L.

Compositions

Electrically conductive or emissive compositions

252512, 252518, 524408, 524409, 524401, 524438, 528487, 528488, 528490, H01B 106

Patent

active

044889860

ABSTRACT:
Electrically conductive polymeric systems having electrical conductivities greater than 10.sup.-4 S/cm are prepared by a method wherein a polyarylene compound which contains one or more chain members of the formula ##STR1## where n is greater than 1, preferably from 5 to 50, R is a nitrile, acid amide, carboxyl or ester group, R.sup.1 and R.sup.2 are each hydrogen or a nitrile, acid amide, carboxyl or ester group, with the proviso that in each case one of the radicals R.sup.1 and R.sup.2 is hydrogen and the other is a nitrile, acid amide, carboxyl or ester group, and Y is an aromatic radical, preferably phenylene, is doped, in the absence of moisture and oxygen, with from 0.03 to 0.9 mole percent of an electron-attracting or electron-donating complexing agent. The resulting electrically conductive polymeric systems are useful in the electrical industry for the production of solar cells, for converting and fixing electromagnetic radiation and for the production of electrical and magnetic switches and electrical storage devices, and can be used for the antistatic treatment of plastics.

REFERENCES:
patent: 4222903 (1980-09-01), Heeger et al.
patent: 4344869 (1982-08-01), Blinne et al.
patent: 4375427 (1983-03-01), Miller et al.
patent: 4395497 (1983-07-01), Naarman et al.
patent: 4440669 (1984-04-01), Ivory et al.

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