Preparation of ditertiarybutyltelluride

Organic compounds -- part of the class 532-570 series – Organic compounds – Selenium or tellurium containing

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C07C39500

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049469940

ABSTRACT:
Ditertiarybutyltelluride and other symmetric dialkyltellurides are prepared from tellurium tetrachloride and metal alkyls in tetrahydrofuran. The reaction product is isolated by filtration followed by vacuum distillation.

REFERENCES:
patent: 4271090 (1981-06-01), Naglieri et al.
W. E. Hoke and P. J. Lemonias, "Low-Temperature Metalorganic Growth of CdTe nd HgTe Films Using Ditertiarybutyltelluride", Applied Physics Letter, vol. 48, No. 24 (Jun. 16, 1986), pp. 1669-1671.
C. H. W. Jones and R. D. Sharma, "The Preparation of Di-t-Butyl Ditelluride and Di-t-Butyl Telluride and the .sup.125 Te NMR and Mossbauer Spectra of Some Dialkyl Tellurides and Ditellurides", Journal of Organometallic Chemistry, vol. 255, (1983), pp. 61-70.
S. Herberg et al., Z. Anorg. Allg. Chem., vol. 492, pp. 95-102 (1982).
S. Herberg et al., Chem. Abstracts, vol. 98, No. 88776q, (1983).

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