Preparation of diarylethanes

Chemistry of hydrocarbon compounds – Compound or reaction product mixture – Aromatic

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585 20, 585 21, 585 23, 585 24, 585422, 585426, C07C 1512, C07C 1516, C07C 208, C07C 212

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059395958

ABSTRACT:
A process for preparing diarylethanes of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen or C.sub.1 -C.sub.8 -alkyl, by reacting aromatic compounds of the general formula II ##STR2## where R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the abovementioned meanings, with styrenes of the general formula III ##STR3## where R.sup.1 has the abovementioned meanings, at from -20 to 300.degree. C. under from 1 to 100 bar in the presence of heterogeneous catalysts, wherein beta-zeolites or mordenites are used as heterogeneous catalysts.

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patent: 5068482 (1991-11-01), Akatsu et al.
patent: 5453555 (1995-09-01), Chang et al.
Hasegawa & Higashimura, "Selective Alkylation of Aromatic Hydrocarbons with Styrene by Solid Polymeric Oxo Acids.", Polymer Journal, vol. 12, No. 6, p. 407 (1980) No Month Available.

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