Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1974-10-29
1977-08-16
Weinberger, Lorraine A.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260389, 260468H, 260469, C07C 6730
Patent
active
040426165
ABSTRACT:
Preparation of tert-(cyclo)alkyl 1-hydrogen-2- hydrocarbylcyclopropanecarboxylates or 1-tert-(cyclo)alkyl spiro [2,p] alkanecarboxylates where p is an integer of at least 2 by reaction of a tert-(cyclo)alkyl 1-hydrogen-2-halocyclopropanecarboxylate with a (1) hydrocarbylmagnesium halide or (2) polymethylene-bis(magnesium halide)- or a magnesiacycloalkane, followed by addition of a proton donor to the reaction product thus obtained.
REFERENCES:
patent: 3823177 (1974-07-01), Fanta
Allinger, Organic Chemistry, p. 425, (1971).
Matsui, Chem. Abst., 68:39156j (1968).
Konzelman, Chem. Abst. 69:105990a, (1968).
Meshcheryakov, Chem. Abst. 54:24436d.
Lukina Chem. Abst. 72:132113k.
Conia, Accounts of Chemical Research, 5 pp. 33-40 (1972).
Uurbanus Elisabeth W.
Verbrugge Pieter A.
Shell Oil Company
Shippen Michael
Weinberger Lorraine A.
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