Preparation of cyclododecene

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Using transition metal-containing catalyst

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585273, 585277, C07C 502

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active

051772787

ABSTRACT:
Partial hydrogenation of 1,5,9-cyclododecatriene to form cyclododecene using ruthenium catalyst and a solvent selected from the group consisting of esters and ethers having a boiling point higher than 245 degrees C.

REFERENCES:
patent: 3925494 (1975-12-01), Fahey
Fahey, Darryl R., "Selective Hydrogenation of 1,5,9-Cyclododecatriene to Cyclododecene Catalyzed by Ru Complexes" J. Org. Ch. 38(1) (1973) pp. 80-87.

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