Preparation of crystalline metal silicate and borosilicate compo

Chemistry of inorganic compounds – Boron or compound thereof – Oxygen containing

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423326, 423328, 423329, 423332, 423333, 502 60, 502 77, 502202, C01B 3320, C01B 3326, C01B 3510

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active

044629710

ABSTRACT:
Crystalline metal silicates and metal borosilicate compositions exhibit useful catalytic properties when the reaction mixture from which they are prepared includes a metal whose oxide precipitates at a pH above 7 and an amount of urea or other compound which upon hydrolysis releases ammonia. The precipitated metal hydroxide is incorporated into the crystalline composition as it forms. These compositions exhibit the X-ray pattern of a ZSM-5 zeolite and have an aluminum content of less than 100 wppm and a composition expressed in terms of its oxides as follows:

REFERENCES:
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patent: 4049573 (1977-09-01), Kaeding
patent: 4208305 (1980-06-01), Kouwenhoven et al.
patent: 4269813 (1981-05-01), Klotz
patent: 4299808 (1981-11-01), Klotz
patent: 4376757 (1983-03-01), Hinnenkamp et al.

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