Preparation of components for refinery blending of...

Mineral oils: processes and products – Refining – Sulfur removal

Reexamination Certificate

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C208S25400R

Reexamination Certificate

active

07491316

ABSTRACT:
The process of the present invention involves reducing the sulfur and/or nitrogen content of a distillate feedstock to produce a refinery transportation fuel or blending components for refinery transportation fuel, by contacting the feedstock with an oxygen-containing gas in an oxidation zone at oxidation conditions in the presence of an oxidation catalyst comprising a zeolitic material, TIQ-6, whose chemical composition corresponds to the formula, expressed as oxides,in-line-formulae description="In-line Formulae" end="lead"?SiO2:zZO2:mMO2:xX2O3:aH2Oin-line-formulae description="In-line Formulae" end="tail"?WhereinZ is Ge, Sn,z is between 0 and 0.25 mol.mol−1M is Ti or Zr,M has a value between 0.00001 and 0.25, preferably between 0.001 and 0.01, anda=has a value between 0 and 2.

REFERENCES:
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patent: 6843978 (2005-01-01), Canos et al.
patent: 6942847 (2005-09-01), Harbuzaru et al.
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patent: WO-01/32809 (2001-05-01), None
Hulea V et al, “Mild Oxidation with H2O2 over Ti-Containing Molecular Sieves—A very Efficient Method for Removing Aromatic Sulfur Compounds from Fuels” Journal of Catalysis, Academic Press, Duluth, MN, US, vol. 198, No. 2, (2001).

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