Preparation of chloroformates having terminal acrylic or methacr

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 6802

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041372530

ABSTRACT:
A process for the preparation of chloroformates having terminal acrylic or methacrylic groups, comprises reacting at least one hydroxyalkyl acrylate or methacrylate with phosgene by introducing a solution of the acrylate or methacrylate into a solution of phosgene, while stirring, at a temperature of -25.degree. C to +5.degree. C, in the presence of an acid acceptor and a stoichiometric excess of phosgene.

REFERENCES:
patent: 2476637 (1949-07-01), Strain et al.
patent: 3619260 (1971-11-01), Parker

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