Preparation of chlorocarboxylic acid chlorides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260544Y, C07C 5346

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active

047643099

ABSTRACT:
Chlorocarboxylic acid chlorides of the formula ##STR1## where R is H or alkyl and n is an integer from 2 to 4, are prepared by reacting a lactone of the formula ##STR2## with phosgene at elevated temperatures and in the presence of a quaternary ammonium salt.

REFERENCES:
patent: 2778852 (1957-01-01), Adams et al.
patent: 3346594 (1967-10-01), Merijan et al.
patent: 3544626 (1970-12-01), Carr et al.
patent: 4321408 (1982-03-01), Maurer et al.
Patai, Saul The Chemistry of Acyl Halides, (1972) Interscience, Publ. pp. 44-45.

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