Preparation of carboxylic acid-containing polyurethane prepolyme

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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528 76, 528 77, C08G 1834

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active

044607385

ABSTRACT:
Disclosed is a process for making carboxylic acid-containing mono- and polyether polyol addition products by reacting maleic acid, fumaric acid, itaconic acid, or mixtures thereof with at least one polyhydroxy-containing mono- or polyether compound (e.g. a polyether diol or triol) in the presence of a peroxy-type free radical initiator. Also disclosed are the processes of making polyurethane prepolymers and aqueous polyurethane dispersions from these carboxylic acid-containing mono- and polyether polyol addition products and processes for using these dispersions in coatings, adhesives and other useful products.

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Functional Monomers Their Preparation, Polymerization and Application, vol. 2, by Ronald H. Yocum and Edwin B. Nyquist, Marchel Dekker, Inc., New York 1974.
D. Dieterich; Polyurethane Ionomers, A New Class of Block Polymers, Angew. Chem. Internat. Edit., vol. 9 (1970), No. 1, pp. 40-50.
V. Malatesta and J. C. Scaiano, Absolute Rate Constants for the Reactions of tert-Butoxyl with Ethers: Importance of the Stereoelectronic Effect, J. Org. Chem., 1982, 47, pp. 1455-1459, Literature Search (NHTIS 82-215) carried out by Olin Corporation.

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