Preparation of carboxylic acid anhydrides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260546, C07C 5154, C07C 5156

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active

040026787

ABSTRACT:
A carboxylic acid anhydride, such as acetic anhydride, is prepared from a carboxylate ester or a hydrocarbyl ether in carbonylation processes comprising the use of an iodide, carbon monoxide and a nickel-chromium catalyst in the presence of a promoter comprising an organo-nitrogen compound or an organo-phosphorus compound wherein the nitrogen and phosphorus are trivalent.

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