Preparation of carboxylic acid alkyl esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260476R, 260485R, 260493, C07C 6704

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039312909

ABSTRACT:
Carboxylic acid alkyl esters are prepared by reacting an halo-alkane with an aqueous solution of an alkali metal salt of a carboxylic acid, using ammonia, a primary amine, a secondary amine, a heavy tertiary amine or a heavy quaternary ammonium salt as the catalyst.

REFERENCES:
patent: 2021852 (1935-05-01), Coleman et al.
Morrison et al., I, "Organic Chemistry," (1966) p. 511.
Morrison et al., II, "Organic Chemistry," (1966) pp. 732-733.
Hennis et al., "I & EC Product Research and Development," (1968) pp. 96-101.
Morrison et al., Organic Chemistry, 2nd Ed., (1966) pp. 511, 666, 668 & 721.
Gilman et al., Organic Chemistry, (1963) p. 751.

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