Preparation of carboxylate and sulfonate salts of 1-cis-(3-chlor

Details Preparation of carboxylate and sulfonate salts of 1-cis-(3-chlor Preparation of carboxylate and sulfonate salts of 1-cis-(3-chlor

1976-01-26

1977-05-17

Ford, John M.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

424249, C07D25172

Patent

active

RE0292265

ABSTRACT:
Compounds of the [formulas] formula ##STR1## wherein X.sup.- is a lower alkyl carboxylate [(I)], a phenylcarboxylate [(I)], a lower alkylsulfonate [(II)] or a phenylsulfonate [(II)] anion, wherein the phenyl ring may have lower alkyl, lower alkoxy, hydroxyl, amino, nitro, bromo or chloro substitution. The compounds are prepared by reacting the [carbinolamine] ring-opened intermediate prepared by reacting cis-1-(3-chloro-2-propenyl)-3,5,7-triaza-1-azoniatricyclo(3.3.1.1.sup.3,7) decane chloride with aqueous sodium hydroxide, with a carboxylic or sulfonic acid, as indicated, to form the corresponding 1-cis-(3-chloro-2-propenyl)-3,5,7-triaza-1-azoniatricyclo(3.3.1.1.sup.3,7) decane carboxylate or sulfonate. These compounds have antimicrobial activity.

REFERENCES:
patent: 3228829 (1966-01-01), Wolf et al.

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