Preparation of carbonylphosphine oxides

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus containing

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568 8, 564 15, 558168, 558192, 558193, 558207, 558214, C07F 940

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056798636

ABSTRACT:
The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides. .alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.

REFERENCES:
patent: 3351681 (1967-11-01), Deinet
patent: 3467622 (1969-09-01), Weil et al.
patent: 3515537 (1970-06-01), Weil et al.

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