Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1984-06-27
1985-10-29
Helfin, Bernard
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
560 12, 560 25, C07C125065, C07C125073
Patent
active
045501882
ABSTRACT:
Disclosed is an improved process for the preparation of carbamates by heating an organic carbonate and an aromatic amine in the presence of aluminum as catalyst and a promoter comprising a combination of iodine and a mercury salt.
High reaction temperatures are avoided by the process and conversions to carbamate products are high. Additionally, the process is economically attractive because even the common aluminum foil can be used as the catalyst.
The products prepared by the process can be used in the production of insecticides, and, particularly, as intermediates in the preparation of organic mono- and polyisocyanates.
REFERENCES:
patent: 2762845 (1956-09-01), Stroh et al.
patent: 3763217 (1973-10-01), Brill
patent: 4100351 (1978-07-01), Romano et al.
patent: 4268683 (1981-05-01), Gurgiolo
patent: 4268684 (1981-05-01), Gurgiolo
patent: 4395565 (1983-07-01), Romano et al.
Frulla Floro F.
Stuber Fred A.
Whitman Peter J.
Helfin Bernard
Jenkins Michael S.
Rose James S.
The Dow Chemical Company
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