Preparation of caprolactam by Beckmann rearrangement of cyclohex

Organic compounds -- part of the class 532-570 series – Organic compounds – Unsubstituted hydrocarbyl chain between the ring and the -c-...

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540540, C07D20104, C07D20116

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active

052645711

ABSTRACT:
A process for preparing caprolactam by Beckmann rearrangement of cyclohexanone oxime with oleum at from 85.degree. to 125.degree. C. in a plurality of rearrangement stages arranged in series entails returning a portion of the reaction mixture leaving the last rearrangement stage to at least one of the preceding rearrangement stages.

REFERENCES:
patent: 3725391 (1973-04-01), Suzuki et al.
patent: 3852273 (1974-12-01), De Rooij
patent: 3953438 (1976-04-01), Smith
patent: 4072678 (1978-02-01), Oyama et al.
patent: 4804754 (1989-02-01), De Decker et al.
patent: 4806638 (1989-02-01), Brand et al.
Derwent Abstract JA7339949 Dec. 29, 1970.

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