Preparation of brominated styrenic polymers or resins

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C525S333400, C525S356000, C525S357000, C525S358000, C525S359100, C525S359200, C525S359300, C525S359400, C525S359500, C525S359600

Reexamination Certificate

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07446153

ABSTRACT:
Bromination of styrenic polymer is carried out in a closed reaction system to retain HX coproduct (where HX is HBr or HCl, or both) in the bromination reaction mixture at superatmospheric pressure. Preferably, the reaction mixture which includes the brominated styrenic polymer and substantially all of the HX coproduct formed is discharged into an aqueous quenching medium. By operating in this manner, the reaction is terminated and the brominated styrenic polymer of desired bromine content and substantially all HX coproduct are captured in the same operation, process equipment costs are reduced, and processing of the reaction mixture is facilitated.

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