Preparation of block copolyether-ester-amides

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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Details

525425, 525434, C08G 6304, C08G 6532

Patent

active

052800873

ABSTRACT:
Disclosed is a novel two-step reaction method for preparing block copolyether-ester-amides. In the first step, caprolactam or other lactam is reacted with a polyether polyol in the presence of a catalyst to form an amino-terminated prepolymer with both a polyamide hard segment and a polyether soft segment. In the second step, the prepolymer is reacted with a dicarboxylic acid as a chain extender to form high molecular weight block copolyether-ester-amides.
The block copolyether-ester-amides prepared by this method are transparent, easily moldable by conventional processing methods such as extrusion and injection molding, and exhibit excellent mechanical properties.

REFERENCES:
patent: 4309518 (1982-01-01), Horlbeck et al.
patent: 4459389 (1984-07-01), Mumcu et al.
patent: 4536563 (1985-08-01), Okitsu et al.
patent: 4874825 (1989-10-01), Gergen et al.

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