Preparation of biuret-containing polyisocyanates

Organic compounds -- part of the class 532-570 series – Organic compounds – Isocyanate esters

Reexamination Certificate

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C560S336000, C564S038000

Reexamination Certificate

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07022874

ABSTRACT:
A process for the preparation of polyisocyanates which contain one or more biuret groups, by reactinga) an aliphatic or cycloaliphatic isocyanate containing two or more isocyanate groups (isocyanate a) withb) a tertiary alcohol or a mixture of water and a tertiary alcohol (biuretizing agent b)at from 100 to 250° C., which comprises carrying out the reaction in the presencec) of a stabilizer (c) which constitutes a catalytic amount of urea, ammonia, biuret, a urea derivative of the formula Iin which R1, R2, R3and R4are hydrogen, C1to C10alkyl or C5to C10aryl, ora carboxamide of the formula IIin which R5is C1to C12alkyl which is unsubstituted or in which 1, 2 or 3 hydrogen atoms are replaced by a radical

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Journal Fur Praktische Chemie Chemiker-Zeitung, cf. H.J. LAAS, et al., vol. 336 (1994) 185-200.

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