Preparation of aryl chloroformates

Organic compounds -- part of the class 532-570 series – Organic compounds – Halocarbonate esters

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C07C 6996

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052741648

ABSTRACT:
A process for the preparation of aromatic aryl chloroformates of the general formula I ##STR1## in which Ar denotes an aryl radical optionally mono- to penta-substituted by C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.3 -C.sub.8 -alkyl-cycloalkyl, C.sub.1 -C.sub.20 -haloalkyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.1 -C.sub.20 -alkylthio, halo, cyano, C.sub.2 -C.sub.20 -alkylcarbonyloxy, C.sub.3 -C.sub.20 -carboalkoxy, formyl, C.sub.2 -C.sub.20 -dialkylamino, aryl, aryloxy, arylthio, aroyl, C.sub.7 -C.sub.20 -aralkyl, C.sub.7 -C.sub.20 -aralkoxy, arylsulfonyl and/or C.sub.7 -C.sub.20 -aralkylthio and/or optionally mono- or di-substituted by chloroformyl and/or nitro, from phosgene and phenols of the general formula II

REFERENCES:
patent: 3170946 (1965-02-01), Kilsheimer et al.
patent: 3211776 (1965-10-01), Stephens
patent: 4085129 (1978-04-01), Semler et al.
patent: 4366102 (1982-12-01), Rauchschwalbe et al.
Ullmanns Encycl. of Tech. Chem., 4 Ed., vol. 9, 381 (1925).

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