Preparation of aromatic azomethines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C11908

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active

044916728

ABSTRACT:
Aromatic azomethines are prepared by reacting anilines with formaldehyde and then removing the greater part of the water by distillation, low-boiling alcohols, in certain amounts, being present during the distillation and, if desired, during the reaction or during a part thereof.
The aromatic azomethines obtainable by the novel process are valuable starting materials for the preparation of herbicides, especially pre-emergence herbicides and post-emergence herbicides, fungicides, insecticides, bacteriostatic agents, fungistatic agents and vulcanization accelerators.

REFERENCES:
patent: 3835191 (1974-09-01), Wagner et al.
Wagner & Zook, "Synthetic Organic Chemistry", pp. 728-729, (1968), Publ. John Wiley and Sons.
Walker, J. Frederic, "Formaldehyde", 3rd Ed., (1964), pp. 369-371, (Reinhold Publishers. (ACS Monograph Series).
Sprung, Murray M., Chemical Reviews, vol. 26, (1940), pp. 297-298, 303-304, and 311-315.
Tollens, Berichte der deut. chem. Gesellschaft, vol. 17, (1884), pp. 657-659.

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