Preparation of an oxy-acetyl compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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260546, 260549, C07C 5112, C07C 5154

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active

046250581

ABSTRACT:
This invention provides a process for producing an oxy-acetyl compound by carbonylating an oxy-methyl compound with carbon monoxide in the presence of a rhodium catalyst, an iodine compound, and a metallic accelerator, and also in the presence of at least one compound selected from the group consisting of boron compounds, bismuth compounds, and tertiary amide compounds in the reaction system. When at least one of the bismuth or boron compound is present in the reaction system, the carbonylation reaction can proceed without precipitation of any metallic accelerator.

REFERENCES:
patent: 4252741 (1981-02-01), Porcelli et al.
patent: 4442304 (1984-04-01), Erpenbach et al.
patent: 4497967 (1985-02-01), Wan

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