Preparation of amines from olefins using certain transition meta

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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564408, 564485, C07C 8502, C07D21100

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active

044543212

ABSTRACT:
Aliphatic and aromatic amines are produced by reacting an olefin with either ammonia or a primary or secondary amine in the presence of a catalytic amount of ruthenium or iron compound catalyst. The reaction is carried out in the liquid phase using an inert liquid, a product amine, or one of the reactants as a solvent. The temperatures used are 100.degree. to 250.degree. C. and the pressures are at least autogenous and up to 12,000 psig.

REFERENCES:
patent: 3412158 (1968-11-01), McClain et al.
patent: 3600413 (1971-08-01), Grimm
patent: 3758586 (1973-09-01), Coulson
patent: 4204997 (1980-05-01), Hobbs et al.
patent: 4215218 (1980-07-01), Diamond et al.
Fieser et al., "Reagents for Organic Synthesis", vol. 3, p. 242 (1972).

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