Preparation of .alpha.-cyano esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C12000, C07C12166

Patent

active

041750934

ABSTRACT:
In the preparation of .alpha.-cyano esters from an acid halide and an aromatic aldehyde in the presence of water, a water-soluble cyanide, a substantially water-immiscible aprotic solvent and optionally a phase transfer catalyst, a stalled reaction is restarted by addition of an alkaline compound capable of generating cyanide ions.

REFERENCES:
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patent: 3996244 (1976-12-01), Fujimoto et al.
patent: 4024163 (1977-05-01), Elliott et al.
patent: 4072752 (1978-02-01), Farooq et al.
patent: 4091110 (1978-05-01), Punja
patent: 4113763 (1978-09-01), Norton
patent: 4123451 (1978-10-01), Sheldon

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