Preparation of alpha, beta-unsaturated enones

Details Preparation of alpha, beta-unsaturated enones Preparation of alpha, beta-unsaturated enones

1995-04-26

1996-04-23

Cook, Rebecca

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568385, 549361, C07C 4500

Patent

active

055105378

ABSTRACT:
A process for oxidizing silyl enone ethers to alpha, beta-unsaturated enodes having the formulas ##STR1## which comprises reacting the appropriate silyl enone ether with a radical generated by the metal catalyst decomposition of a peroxide composition.

REFERENCES:
patent: 4215044 (1980-07-01), Middleton
patent: 4603212 (1986-07-01), White
patent: 4908451 (1990-03-01), Tanaka et al.
Holger et al., Journal of the American Chemical Society, vol. 107, No. 1, pp. 268-270 (1985).
Hosokawa et al., Chemistry Letters, No. 7, pp. 1081-1082 (1983).
D. R. White, et al., Tetrahedron Letters, vol. 30, No. 12, 1469-1472 (1989).
Rubottom et al. J. Org. Chem. 43(8) 1978 1599-1602.
Beckworth et al, J. Amer. Chem. Soc 1985 1986! 108, 8230-8234.
Kharasch et al, J. Organ. Chem., 1953, 18, 322-327.
Kaneda et al, Tet. Let., 1981, 2595-2598.

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