Preparation of .alpha.-acetoxy aldehydes and ketones

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260327M, C07C 6728

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active

039651576

ABSTRACT:
An improved method for the preparation of intermediates of formula: ##EQU1## WHERE R.sup.1 and R.sup.2 represent hydrogen, C.sub.1.sub.-4 alkyl, C.sub.1.sub.-4 hydroxyalkyl, C.sub.3.sub.-10 cycloalkyl, C.sub.3.sub.-6 acyloxyalkyl, or phenyl, by mercuric ion assisted hydrolysis of the corresponding dithianes, and novel intermediates thereby produced.

REFERENCES:
patent: 2156721 (1939-05-01), Simo et al.
patent: 2198172 (1940-04-01), McGill
patent: 2726260 (1955-12-01), Novello
patent: 2834792 (1958-05-01), Wilkinson, Jr. et al.
patent: 2892865 (1959-06-01), Giraldi et al.

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