Preparation of alkyl formamides

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564123, 564215, C07C23110

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active

059199792

ABSTRACT:
This invention relates to an improvement in a process for the production of an alkyl formamide, wherein a gas-containing carbon monoxide is reacted at elevated temperature and pressure in reaction zone with a nitrogen-containing compound selected from the group consisting of ammonia, a primary or secondary alkylamine, in the presence of a solvent and a catalyst. The improvement comprises utilizing a solvent comprising a polyethylene glycol, polypropylene glycol, polyethylenepropylene glycol, or mixtures, and an alkali metal or alkaline earth metal alkoxide of a polyethylene glycol, polypropylene glycol, polyethylenepropylene glycol or mixtures as the catalyst.

REFERENCES:
patent: 4098820 (1978-07-01), Couteau et al.
patent: 4101577 (1978-07-01), Smathers
patent: 4761499 (1988-08-01), Epstein

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