Preparation of alkyl cyanoacetates

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C12004

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043223699

ABSTRACT:
The alkyl cyanoacetates are prepared by reacting an alkyl chloracetate with an excess of an alkali metal cyanide, in an inert solvent and in the presence of at least one tertiary amine sequestering agent having the formula:

REFERENCES:
patent: 2928877 (1960-03-01), Jaul et al.
patent: 2985682 (1961-05-01), Raffelson
patent: 3360540 (1967-12-01), Sennewald et al.
patent: 3384654 (1968-05-01), Sennewald et al.
patent: 3773808 (1973-11-01), Wesselman
patent: 4174347 (1979-11-01), Bertola
Hackh's Chemical Dictionary, 4th Ed., (1969), pp. 240, 605 and 650.

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