Preparation of alkyl adipates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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C07C 6736

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056707010

ABSTRACT:
The alkyl adipates are prepared by reacting admixture consisting essentially of alkyl 3-pentenoate and alkyl 2-pentenoate with carbon monoxide and an alcohol, at elevated temperature, under superatmospheric pressure and in the presence of a catalytically effective amount of cobalt or a cobalt compound and a nitrogenous heterocyclic base.

REFERENCES:
Akio Matsuda, "The Cobalt Carbonyl-catalyzed Hydroesterification of Butadiene with Carbon Monoxide and Methanol", Bulletin of the Chemical Society of Japan, vol. 46 (1973), pp. 524-530.

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