Preparation of alkanols which are substituted in the 1 position

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546152, 568715, C07D21328, C07C 3322, C07C 3334

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active

049963244

ABSTRACT:
##STR1## where R.sup.1 is an aromatic or heterocyclic radical, R.sup.2 is a straight-chain or branched alkyl raical and R.sup.3 is hydrogen, methyl or ethyl, are prepared by reacting a secondary alcohol of the formula ##STR2## with a primary alcohol of the formula R.sup.2 OH (III) in the presence of an alkali metal hydroxide at from 150.degree. to 300.degree. C.

REFERENCES:
The Merck Index, Ninth Edition, p. ONR-39, published by Merck and Co., Inc. (1976).
Angew. Chem. 64 (1952), pp. 213-220.
Bulletin Soc. Chem. France, 1983, II. pp. 252-256.
Tetrahedron, 23 (1967) pp. 1723-1733.

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