Preparation of alkali-metal azides

Chemistry of inorganic compounds – Nitrogen or compound thereof – Binary compound

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C01B 2108

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040655482

ABSTRACT:
Alkali-metal azide is prepared and purified from a slurry of alkali-metal azide/alkali metal hydroxide double salt in liquid ammonia by settling a layer of double salt from the slurry, separating the balance of the slurry from the double salt layer, then dissolving the layer in water and recovering purified alkali-metal azide from the water solution by crystallization.

REFERENCES:
patent: 3455648 (1969-07-01), Shaw et al.
"Chemical Abstracts" vol. 54; 1960, p. 4225i & 4226.
Supplement To Mellor's Comp. Treatise on Inor. & Theoretical Chem.; Sup. II, vol. 8; John Wiley & Sons; N. Y., 1967, pp. 16-18.

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