Preparation of aliphatic dinitriles

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C12000, C07C12120, C07C12126

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039819000

ABSTRACT:
The addition of a free metal of group VIII of the Periodic Table or of one of its oxides or hydroxides to acrylonitrile heated under a hydrogen pressure of 1 to 50 bars in the presence of a ruthenium derivative as catalyst improves the rate of conversion of the acrylonitrile into 1,4-dicyanobutenes and/or adiponitrile.

REFERENCES:
patent: 3459785 (1969-08-01), Jones
patent: 3562181 (1971-02-01), Linn et al.

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