Preparation of addition polymerization catalysts

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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534 15, 502103, 502117, 526160, 526943, 556 12, 556 21, 556 53, 987 2, C07F 1700, C07F 700

Patent

active

061180130

ABSTRACT:
Metal complexes useful as components of addition polymerization catalysts are prepared by oxidizing Group 4 or Lanthanide metal containing complexes using an organic halide oxidizing agent in a unique one electron oxidation.

REFERENCES:
patent: 5455333 (1995-10-01), Stickler et al.
Szymoniak, Jan, et al., Inorganica Chimica Acta, 180 (1991) 153-160.
Reetz, Manfred T, Organotitanium Reagent in Organic Synthesis, Springer-Verlag, Berlin Heidelberg New York Tokyo, p. 181.
Pearson, Anthony J., Metallo-organic Chemistry, Wiley & Sons, pp. 114-116 (1985).
Collman, J. et al., Principles and Applications of Organotransition Metal Chemistry, University Science Books, 1987, 274-294; 307-309.

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