Preparation of acetic acid and methyl acetate

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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502184, 502185, 502245, 502259, 502326, 562519, C07C 5112, C07C 5308, C07C 6736, C07C 6914

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active

049182188

ABSTRACT:
Preparation of acetic acid and methyl acetate by gas-phase carbonylation of methanol in the presence of a nickel-containing catalyst and in the presence of chlorine, bromine or iodine or a volatile compound of one of these halogens as a promoter, wherein the active material of the catalyst used consists of not less than 40% by weight of nickel and the catalyst contains 0.001-1 part by weight of palladium per part by weight of nickel, as well as supported catalysts whose active material contains Ni and Pd in the above ratio.

REFERENCES:
patent: 2650245 (1953-08-01), Thomas et al.
patent: 2650246 (1953-08-01), Thomas et al.
patent: 3856856 (1974-12-01), Nozaki

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