Preparation of 4,4,4-trifluoro-2-methyl-1-butene by the dehydroc

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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C07C 2118

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052762220

ABSTRACT:
The partially fluorinated alkene 4,4,4-trifluoro-2-methyl-1-butene is produced by the selective dehydrochlorination of 3-chloro-1,1,1-trifluoro-3-methylbutane in the presence of a suitable base at elevated temperatures. The alkene is converted to 1,2-epoxy-4,4,4-trifluoro-2-methylbutane which is polymerizable in the presence of an aluminum coordination catalyst. A copolymer can be made with epichlorohydrin.

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March, J. Advanced Organic Chem 1977 p. 935 "Dehydrohalogenation of Alkyl Halides".

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