Preparation of 3-buten-1-ol from 3,4-epoxy-1-butene

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568907, 5689095, 568900, C07C 2910, C07C 33025

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active

061039438

ABSTRACT:
Disclosed is a process for the synthesis of 3-buten-1-ol by contacting 3,4-epoxy-1-butene and formic acid with a homogeneous catalyst solution comprising a palladium(0) compound, a tertiary phosphine and a trialkylamine dissolved in tetrahydrofuran.

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patent: 5600034 (1997-02-01), Mori et al.
J. Tsuji et al., Chem. Letters, 1017 (1984).
J. Tsuji et al., Tetrahedron Letters, No. 7, pp. 613-616 (1979).

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