Preparation of 3, 3-dimethylbutyraldehyde from a tert-butyl cati

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568449, 568488, C07C 4550

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active

059774150

ABSTRACT:
This invention provides a method for preparing 3,3-dimethylbutyraldehyde from a tert-butyl cation precursor and vinyl chloride. The tert-butyl cation precursor is contacted with vinyl chloride in the presence of an inorganic acid, and the product is allowed to react with water to form 3,3-dimethylbutyraldehyde.

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K. Bott,"Erzeugung und Reaktionen von 1-Adamantyl-vinyl-Kationen", Liebigs Ann. Chem., vol. 766, pp. 51-57 (1972).
K. Bott, "Tscherniac-Einhorn-Synthesen mit Chlorolefin und Acetylen", Chem. Ber., vol. 106, pp. 2513-2522 (1973).
K. Bott, "Aldehydsynthesen Mit 1,2-Dichlorathylen und Vinylchlorid", Tetrahedron Lett., No. 49, pp. 4301-4304 (1970).

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