Preparation of 2,2-dihydrocarbyl-3-propiolactones

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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528417, C07D30512

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active

051552370

ABSTRACT:
2,2-Dihydrocarbyl-3-propiolactones are prepared by the thermolysis at 175.degree. C. to 350.degree. C. of low molecular weight (oligomeric) poly(3-hydroxy-2,2-dihydrocarbylpropionic acid) that contains carboxyl ends groups, in the presence of alkali metal, ammonium or phosphonium cations. The propiolactones may be polymerized to high molecular weight polymers.

REFERENCES:
patent: 3751435 (1973-08-01), van der Ven
patent: 4550181 (1985-10-01), Murib et al.
T. L. James et al., J. Am. Chem. Soc., vol. 91, pp. 7743-7746 (1969).
L. E. Manring et al., Macromolecules, vol. 23, pp. 1902-1907 (1990).

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