Preparation of 1,3-dienamines from myrcene and substituted myrce

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564384, 564485, 544336, C07C 8518

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045337519

ABSTRACT:
There is provided a process for the addition of a secondary aliphatic amine to myrcene or an 8-substituted myrcene and isomerization to a dialkyl 1,3-dienamine. The process is liquid phase and employs an excess of the amine relative to myrcene or substituted myrcene. The catalyst is an alkali metal amide anion formed from the amine.

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