Preparation of 1,3,5,7 tetraacetamido- and 1,3,5,7-tetraaminoada

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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564414, 564457, B01J 1912

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active

042844843

ABSTRACT:
1,3,5,7--Tetraacetamidoadamantane is prepared by reacting 1,3,5,7--tetraiadamantanewith acetonitrile and water in the presence of actinic radiation. The 1,3,5,7--tetraacetamidoadamantane can be hydrolyzed with hydrochloric acid to produce 1,3,5,7--tetraaminoadamantane tetrahydrochloride, which can be converted to the free base by treatment with an equivalent amount of an alkali, e.g. aqueous sodium hydroxide.

REFERENCES:
patent: 3419611 (1968-12-01), Moore
patent: 3523137 (1970-08-01), Moore
patent: 3591642 (1971-07-01), Szinai et al.
patent: 3985803 (1976-10-01), Inamoto et al.
Stetter et al., Chem. Ber. 93 (1960), p. 1366.

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